No 5-6 2024
To Prof. Vasile Pârvulescu on the occasion of his 70th anniversary
Rev. Roum. Chim., 2024, 69(5–6), 237–240
1. Răzvan ȘUTEU, Cristian SILVESTRU and Anca SILVESTRU
Hypercoordination in triorganoantimony(III) compounds. Case study of heteroleptic [2,6-(Me2NCH2)2C6H3]2(Ph)SbDOI: 10.33224/rrch.2024.69.5-6.01
Rev. Roum. Chim., 2024, 69(5–6), 241–245
Key words: heteroleptic triorganoantimony(III) compound, hypercoordination, solution behaviour, single-crystal X-ray diffraction
2. Cristina TABLET, Iulia MATEI, Sorana IONESCU and Mihaela HILLEBRAND
Experiental and theoretical ECD study of the 7-methoxycoumarin-3-carboxylic acid binding to BSA
DOI: 10.33224/rrch.2024.69.5-6.02
Rev. Roum. Chim., 2024, 69(5–6), 247–253
Key words: coumarin, serum albumin, induced circular dichroism, time-dependent density functional theory.
3. Eszter LAKATOS, Niculina Daniela HĂDADE, Elena BOGDAN, Anamaria TEREC and Ion GROSU
Suzuki-Miyaura, Sonogashira cross-coupling and CuACC reactions suite for the access to a large macrocycle with m,m’-terphenyl motif
DOI: 10.33224/rrch.2024.69.5-6.03
Rev. Roum. Chim., 2024, 69(5–6), 255–262
Key words: large macrocycle, m,m’-terphenyl, Suzuki-Miyaura cross coupling, Sonogashira cross -coupling, CuAAC reaction.
4. Gheorghe MARIA, Cristiana Luminita GIJIU, Laura RENEA and Daniela GHEORGHEIn-silico optimal operating policies of a batch or a fed-batch bioreactor for mAb production using a hybridoma cell culture
DOI: 10.33224/rrch.2024.69.5-6.04
Rev. Roum. Chim., 2024, 69(5–6), 263–278
Key words: monoclonal antibodies (mAbs) production maximization, hybridoma cell culture, batch/fedbatch bioreactor optimization, raw material consumption minimization, time stepwise operating policy.
5. Ștefan DIMITRIU, Mihai RĂDUCĂ, Victorița TECUCEANU, Anamaria HANGANU and Marius ANDRUH
Alkylation of morpholine with 2-(chloromethyl)-nitronyl-nitroxide: a new ligand and its nickel complex
DOI: 10.33224/rrch.2024.69.5-6.05
Rev. Roum. Chim., 2024, 69(5–6), 279–284
Key words: nitronyl nitroxide ligands, nickel(II) complex, crystal structures.
6. Giuseppe STOIAN, Elena E. TOMA, Petruta OANCEA, Natalia Candu, Bogdan COJOCARU, Madalina TUDORACHE and Simona M. COMAN
CQDs-based nanocomposites for the 5-(hydroxymethyl)furfural photooxidation
DOI: 10.33224/rrch.2024.69.5-6.06
Rev. Roum. Chim., 2024, 69(5–6), 285–290
Key words: carbon quantum dotsș TiO2/CQD heterostructures, photooxidation, HMF, FDCA.
7. Rodica ZĂVOIANU, Bogdan E. COJOCARU, Sabina G. ION, Ana Paula SOARES DIAS, Anca CRUCEANU and Octavian D. PAVEL
The influence of the precursor type in the synthesis of Mg/Al-hydrotalcite through a non-traditional method used for Claisen-Shmidt condensation
DOI: 10.33224/rrch.2024.69.5-6.07
Rev. Roum. Chim., 2024, 69(5–6), 291–300
Key words: Mg/Al-hydrotalcites; co-precipitation / mechanochemical routes; organic alkalis; Claisen-Schmidt condensation.
8. Funda OZKOK, Demet SEZGIN MANSUROGLU, Pinar OZ, Kamala ASGAROVA, Yesim Muge SAHIN, Nihal ONUL and Tunc CATALSynthesis of a novel thio-anthraquinone derivative-based tissue dye
DOI: 10.33224/rrch.2024.69.5-6.08
Rev. Roum. Chim., 2024, 69(5–6), 301–307
Key words: brain, neurange dye, thioanthraquinone
9. Soumaya LAROUS, Nadjet BOULKROUNE, Racha Chiraz OUGOUR and Nourhen Nada M’ZAHEM
Study of quaternary liquid-liquid equilibria for systems (water/ methanol/ cyclohexanol+ toluene): Experimental and modelling
DOI: 10.33224/rrch.2024.69.5-6.09
Rev. Roum. Chim., 2024, 69(5–6), 309–319
Key words: liquid-liquid equilibrium, quaternary system, NRTL model, separation factor, distribution coefficient.
10. Samet POYRAZ, H. Ali DÖNDAŞ, Samet BELVEREN and Hayati SARI
Acid ionization constant of potential bioactive functionalized N benzoylthiourea/ 2-thiohydantoin-pyrrolidine derivatives by potentiometric titration in acetonitrile-waterDOI: 10.33224/rrch.2024.69.5-6.10
Rev. Roum. Chim., 2024, 69(5–6), 321–329
Key words: ionization constant, pyrrolidine, potentiometric titration, thiohydantoin, N-benzoylthiourea.
11. Alexandru T. BALABAN, Marilena FERBINTEANU, Elena HRISTEA, Rodica BARATOIU and Petre IONITA
Unexpected rearrangement of phenoxypicramide to 1,3-dinitro-10H-phenoxazineDOI: 10.33224/rrch.2024.69.5-6.11
Rev. Roum. Chim., 2024, 69(5–6), 331–336
Key words: free radical, phenoxazine, mechanism, synthesis, rearrangement, alkoxyl picramide.